Studies on the complex formation of iron with humic substances [Translation from: Vom Wasser 53, 243-247, 1979]

Frimmel, F.H. (1983) Studies on the complex formation of iron with humic substances [Translation from: Vom Wasser 53, 243-247, 1979]. Windermere, UK, Freshwater Biological Association, (FBA Translations (New Series), 164)

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Abstract

Most of the humic substances which occur in natural waters have an iron content of a few percent, indicated by the mg/1 content of organically-bonded carbon. This iron is apparently bound in a complex with the humic substances, for it quite plainly differs in its chemical and physico-chemical properties from what one would expect from the purely inorganic iron-water system. The deviations range from the solubility to the redox behaviour, and thus are frequently the basis of analytical and technical difficulties. The key to the solution of most of this problem lies in a better understanding of the aforementioned bonds between the iron and the humic substances. This paper studies the iron content of the humic substance concentration from a bog lake sample and the complexing of iron by humic substances from the surface of the bog lake.

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